06.11.2025
New article published: 🌍 Temporal change of arsenic in Sargassum spp. biomass deposit: mass balance, speciation and microbial biotransformation pathways
🌊🧪🦠The decomposition of Sargassum washed ashore poses a significant environmental problem due to the release of arsenic (As). In a 120-day mesocosm experiment under natural conditions, the fate of As in biomass, leachate, and gas phases was investigated. Fresh Sargassum contained 85 mg As/kg (dry weight), mainly as AsIII. In the leachate, the As concentration was initially 10 mg/L and decreased to 1.5 mg/L after 90 days, with AsV dominating. Volatile arsenic compounds, especially trimethylarsine, were also released at an early stage. After 120 days, about 50% of the original arsenic had passed into the leachate, while 0.06‰ escaped into the atmosphere. Despite considerable mass loss, 55 mg As/kg remained in the residual biomass. The increasing bacterial diversity indicates a central role of microorganisms in As conversion. The measured values often exceed the French limits for hazardous waste.🦠🧪🌊